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Of the 63 samples, SERMs were declared in 21 (33.3%), AIs in 16 (25.4%), and other PCT substances in 26 (41.3%)

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The reduction of roGFP2(S 2 ) is therefore a good example for an enzyme using an alternative reaction pathway to overcome a kinetic challenge, and we hypothesize that other non-glutathione disulfide substrates with reactive proximal cysteinyl residues and rather negative redox potentials also require a ternary complex for their reduction